Thin film solar cell

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Cross-section of a thin-film polycrystalline solar cell.

A thin-film solar cell (TFSC), also called a thin-film photovoltaic cell (TFPV), is a solar cell that is made by depositing one or more thin layers (thin film) of photovoltaic material on a substrate. The thickness range of such a layer is wide and varies from a few nanometers to tens of micrometers.

Many different photovoltaic materials are deposited with various deposition methods on a variety of substrates. Thin-film solar cells are usually categorized according to the photovoltaic material used:

 \begin{pmatrix}\mathrm{Cu}\\\mathrm{Ag}\\\mathrm{Au}\end{pmatrix} \begin{pmatrix}\mathrm{Al}\\\mathrm{Ga}\\\mathrm{In}\end{pmatrix} \begin{pmatrix}\mathrm{S} \\\mathrm{Se}\\\mathrm{Te}\end{pmatrix}_2

Possible combinations of Group-(XI, XIII, XVI)
elements in the periodic table that yield
a compound showing photovoltaic effect
(Cu, Ag, Au

History[edit]

Initially appearing as small strips powering hand-held calculators, thin-film PV is now available in very large modules used in sophisticated building-integrated installations and vehicle charging systems. GBI Research, a private company selling reports it calls "global business intelligence", projects thin film production to grow 24% from 2009 levels and to reach 22,214 MW in 2020. "Expectations are that in the long-term, thin-film solar PV technology would surpass dominating conventional solar PV technology, thus enabling the long sought-after grid parity objective."[1][2]

Thin-film silicon[edit]

A silicon thin-film cell uses amorphous (a-Si or a-Si:H), protocrystalline, nanocrystalline (nc-Si or nc-Si:H) or black silicon. Thin-film silicon is opposed to wafer (or bulk) silicon (monocrystalline or polycrystalline).

Design and fabrication[edit]

The silicon is mainly deposited by chemical vapor deposition, typically plasma-enhanced (PE-CVD), from silane gas and hydrogen gas. Other deposition techniques being investigated include sputtering and hot wire techniques.

The silicon is deposited on glass, plastic or metal which has been coated with a layer of transparent conducting oxide (TCO).

A p-i-n structure is usually used, as opposed to an n-i-p structure. This is because the mobility of electrons in a-Si:H is roughly 1 or 2 orders of magnitude larger than that of holes, and thus the collection rate of electrons moving from the n- to p-type contact is better than holes moving from p- to n-type contact. Therefore, the p-type layer should be placed at the top where the light intensity is stronger, so that the majority of the charge carriers crossing the junction would be electrons.[3]

Micromorphous silicon[edit]

Micromorphous silicon module technology combines two different types of silicon, amorphous and microcrystalline, in a top and a bottom photovoltaic cell. These two materials are chosen because their different absorption spectrums and easily combined process. Because the two different materials are both Si, they can be manufactured in the same technology, which now is PECVD. The band gap of a-Si is 1.7 eV and that of c-Si is 1.1 eV, which eventually broaden the spectral acceptance of the micromorph tandem solar cell. The c-Si layer can help to absorb the energy of red and infrared spectrum and increase the overall efficiency. The best efficiency can be achieved at transition between a-Si and c-Si. Use of protocrystalline silicon for the intrinsic layer has shown to optimize the open-circuit voltage of an a-Si photovoltaic cell.[4]

Efficiency[edit]

Solar cell efficiencies of various cell technologies as tracked by NREL [5]

These types of silicon present dangling and twisted bonds, which results in deep defects (energy levels in the bandgap) as well as deformation of the valence and conduction bands (band tails). The solar cells made from these materials tend to have lower energy conversion efficiency than bulk silicon (also called crystalline or wafer silicon), but are also less expensive to produce. The quantum efficiency of thin-film solar cells is also lower due to reduced number of collected charge carriers per incident photon.

Amorphous silicon has a higher bandgap (1.7 eV) than crystalline silicon (c-Si, 1.1 eV), which means it absorbs the visible part of the solar spectrum more strongly than the infrared portion of the spectrum. As nc-Si has about the same bandgap as c-Si, the nc-Si and a-Si can advantageously be combined in thin layers, creating a layered cell called a tandem cell. The top cell in a-Si absorbs the visible light and leaves the infrared part of the spectrum for the bottom cell in nc-Si.

Recently, solutions to overcome the limitations of thin-film silicon have been developed. Light trapping schemes where the incoming light is obliquely coupled into the silicon and the light traverses the film several times enhance the absorption of sunlight in the films. Thermal processing techniques enhance the crystallinity of the silicon and pacify electronic defects.[6]

Building integrated photovoltaics[edit]

Thin film photovoltaic laminates being installed onto a roof.

Thin film solar panels are commercially available for installation onto the roofs of buildings, either applied onto the finished roof, or integrated into the roof covering. The advantage over traditional PV panels is that they are very low in weight, are not subject to wind lifting, and can be walked on (with care). The comparable disadvantages are increased cost and reduced efficiency.

A silicon thin film technology is being developed for building integrated photovoltaics (BIPV) in the form of semitransparent solar cells which can be applied as window glazing. These cells function as window tinting while generating electricity.

Organic solar cells[edit]

An organic solar cell would use a photovoltaic polymer compound to produce electricity. Current research devices show low efficiency and stability. If an organic solar cell of usable efficiency can be developed, it may reduce the cost of PV installations.

Efficiencies, volumes and prices[edit]

Since the invention of the first modern silicon solar cell in 1954, incremental improvements have resulted in modules capable of converting 12 to 18 percent of solar radiation into electricity.[7] The performance and potential of thin-film materials are high, reaching cell efficiencies of 12–20%; prototype module efficiencies of 7–13%; and production modules in the range of 9%. Future module efficiencies are expected to climb close to the state-of-the-art of today's best cells, or to about 10–16%.[8] The thin film cell prototype with the best efficiency reaches 20.4% (First Solar), which is comparable to the best conventional solar cell prototype efficiency of 25.6% (Panasonic)[9][10]

Annual manufacturing volume in the United States has grown from about 12 megawatts (MW) per year in 2003 to more than 20 MW/yr in 2004; 40–50 MW/yr production levels were expected in 2005 with continued rapid growth in the years after that.

Costs are expected to drop to below $100/m2 in volume production, and could reach even lower levels—well under $50/m2, the DOE/NREL goal for thin films—when fully optimized. At these levels, thin-film modules will cost less than fifty cents per watt to manufacture, opening new markets such as cost-effective distributed power and utility production to thin-film electricity generation.[11]

As crystalline silicon price rose, the production cost of crystalline silicon-based solar cell module in 2008 was at some point 4–5 times higher than that of thin film modules. Thin-film producers still enjoy in 2009 price advantage as its production cost is 20% less than that of silicon modules. It is expected that the production cost of thin-film will continue dropping (40% less than silicon), as Chinese producers are now putting more resources into R&D and partnering with manufacturing equipment suppliers.[12]

Production, cost and market[edit]

In recent years, the manufacturers of thin-film solar modules have brought costs down and gained competitive strength through advanced thin film technology. However, the traditional crystalline silicon technologies will not give up their market positions for a few years because they still hold considerable development potential in terms of the cost. Efficiency of thin film solar is considerably lower and thin film solar manufacturing equipment suppliers intend to score costs of below USD 1/W, and Anwell Technologies Limited claimed that they intend to bring it down further to USD 0.5/W.[13] In July 2013 the price of Thin film a-Si dropped to €0.38/Wp,[14] about USD 0.502493.[15] Those equipment suppliers have been doing R&D for micro-morphous silicon modules since 2008. This technology represents a development based on the thin-film panels made of ordinary amorphous silicon marketed at present that brings higher cell efficiency by depositing an additional absorber layer made of micro crystalline silicon on the amorphous layer. Some equipment suppliers even claim that there will be machinery in market to manufacture these new modules at $0.70.[16] With such potential of further development of thin film solar technology, the European Photovoltaic Industry Association (EPIA) expects that manufacturing capacities for these technologies will double to over 4GW by 2010 representing a market share of around 20%.[17] In 2011, GE announced plans to spend $600 million on a new CdTe solar cell plant and enter this market.[18]

Potential thin film manufacturers faced severe price competition from Chinese refiners of silicon and manufacturers of conventional solar panels. As of January, 2013 one of the consequences was that some firms developing thin film technology together with their patents have been sold to Chinese firms below cost.[19]

Installations[edit]

First Solar, the CdTe thin-film manufacturer stated that "at the end of 2007, over 300 MW of First Solar PV modules had been installed worldwide." Below is a list of several recent installations:[8]

Denver-based Conergy Americas and officials at California's South San Joaquin Irrigation District (SSJID)[27] have installed what is believed to be the world's first single-axis solar tracking system featuring thin-film photovoltaic cells.[28]

Time Award[edit]

Thin-film photovoltaic cells are included in the TIME's Best Inventions of 2008.[29]

See also[edit]

References[edit]

  1. ^ Renewable Energy Magazine[dead link]
  2. ^ GBI Research (2011). "Thin Film Photovoltaic PV Cells Market Analysis to 2020 CIGS Copper Indium Gallium Diselenide to Emerge as the Major Technology by 2020". gbiresearch.com. Retrieved 29 January 2011. 
  3. ^ "Amorphes Silizium für Solarzellen" (in German). 
  4. ^ J. M. Pearce, N. Podraza, R. W. Collins, M.M. Al-Jassim, K.M. Jones, J. Deng, and C. R. Wronski (2007). "Optimization of Open-Circuit Voltage in Amorphous Silicon Solar Cells with Mixed Phase (Amorphous + Nanocrystalline) p-Type Contacts of Low Nanocrystalline Content". Journal of Applied Physics 101: 114301. doi:10.1063/1.2714507. 
  5. ^ "NREL: Best PV research cell efficiencies". Retrieved 25 November 2012. 
  6. ^ Renewable Sources
  7. ^ Steve Heckeroth (February–March 2010). "The Promise of Thin-Film Solar". Mother Earth News. Retrieved 2010-03-23. 
  8. ^ a b Utility-Scale Thin-Film: Three New Plants in Germany Total Almost 50 MW
  9. ^ Yet Another Solar Cell Efficiency Record For First Solar
  10. ^ Panasonic HIT Solar Cell Sets World Efficiency Record
  11. ^ About the Thin Film Partnership Program
  12. ^ Yotam Ariel and Coco Liu (December 14, 2009). "Chinese Manufacturers Eye Thin-film PV Market". 
  13. ^ "ANWELL produces its first solar panel". NextInsight. 2008-09-01. 
  14. ^ http://www.solarserver.com/service/pvx-spot-market-price-index-solar-pv-modules.html
  15. ^ http://www.xe.com/currencyconverter/convert/?Amount=0.38&From=EUR&To=USD (Mid-market rates: 2013-08-31 21:20 UTC 1 EUR = 1.32235 USD)
  16. ^ "Photovoltaics: Thin-film technology about to make its breakthrough". Solar server. 2008-08-07. 
  17. ^ "EPIA projects a rosy picture for the thin film industry". Thin film today. 
  18. ^ Peralta, Eyder. (2011-04-07) GE Unveils Plans To Build Largest Solar Panel Factory In U.S. : The Two-Way. NPR. Retrieved on 2011-05-05.
  19. ^ Diane Cardwell; Keith Bradsher (January 9, 2013). "Chinese Firm Buys U.S. Solar Start-Up". The New York Times. Retrieved January 10, 2013. 
  20. ^ "Germany’s largest thin-film pitched roof system begins production". PV-tech. 28 October 2008. 
  21. ^ "California Utility to Install 250MW of Roof-Top Solar". SustainableBusiness.com. 2008-03-27. 
  22. ^ "First Solar announces two solar projects with Southern California Edison". Semiconductor-Today.com. 2008-07-17. 
  23. ^ First Solar to Build 10 MW Solar PV Power Plant for Sempra Generation
  24. ^ Wenzel, Elsa. (2008-07-24) First Solar and Sempra plan thin-film solar plant | Green Tech – CNET News. News.cnet.com. Retrieved on 2011-05-05.
  25. ^ "Report at juwi.de". 
  26. ^ "Greening Up The House". Miami Herald. April 19, 2008. 
  27. ^ the homepage of the South San Joaquin Irrigation District
  28. ^ Conergy Brings World's First Known Thin-Film Solar Energy Tracking System – and $400,000 In Annual Utility Bill Savings – to California's South San Joaquin Irrigation District
  29. ^ "25. Thin-Film Solar Panels". Time. 2008-10-29. TIME's Best Inventions of 2008. Retrieved 2010-05-25. 

Sources[edit]

External links[edit]