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A soap bubble is an extremely thin film of soapy water enclosing air that forms a hollow sphere with an iridescent surface. Soap bubbles usually last for only a few seconds before bursting, either on their own or on contact with another object. They are often used for children's enjoyment, but they are also used in artistic performances. Assembling several bubbles results in a foam.
When light shines onto a bubble it appears to change colour. Unlike those seen in a rainbow, which arise from differential refraction, the colours seen in a soap bubble arise from interference of light reflecting off the front and back surfaces of the thin soap film. Depending on the thickness of the film, different colours interfere constructively and destructively.
Soap bubbles are physical examples of the complex mathematical problem of minimal surface. They will assume the shape of least surface area possible containing a given volume. A true minimal surface is more properly illustrated by a soap film, which has equal pressure on inside as outside, hence is a surface with zero mean curvature. A soap bubble is a closed soap film: due to the difference in outside and inside pressure, it is a surface of constant mean curvature.
While it has been known since 1884 that a spherical soap bubble is the least-area way of enclosing a given volume of air (a theorem of H. A. Schwarz), it was not until 2000 that it was proven that two merged soap bubbles provide the optimum way of enclosing two given volumes of air of different size with the least surface area. This has been dubbed the double bubble conjecture.
Due to these qualities soap bubbles films have been used with practical problem solving application. Structural engineer Frei Otto used soap bubble films to determine the geometry of a sheet of least surface area that spreads between several points, and translated this geometry into revolutionary tensile roof structures. A famous example is his West German Pavilion at Expo 67 in Montreal.
When two bubbles merge, they adopt a shape which makes the sum of their surface areas as small as possible, compatible with the volume of air each bubble encloses. If the bubbles are of equal size, their common wall is flat. If they aren't the same size, their common wall bulges into the larger bubble, since the smaller one has a higher internal pressure than the larger one, as predicted by the Young–Laplace equation.
At a point where three or more bubbles meet, they sort themselves out so that only three bubble walls meet along a line. Since the surface tension is the same in each of the three surfaces, the three angles between them must be equal to 120°. Only four bubble walls can meet at a point, with the lines where triplets of bubble walls meet separated by cos−1(−1/3) ≈ 109.47°. All these rules, known as Plateau's laws, determine how a foam is built from bubbles.
Bubbles can be effectively used to teach and explore a wide variety of concepts to even young children. Flexibility, colour formation, reflective or mirrored surfaces, concave and convex surfaces, transparency, a variety of shapes (circle, square, triangle, sphere, cube, tetrahedron, hexagon), elastic properties, and comparative sizing, as well as the more esoteric properties of bubbles listed on this page. Bubbles are useful in teaching concepts starting from 2 years old and into college years. A Swiss university professor, Dr. Natalie Hartzell, has theorized that usage of artificial bubbles for entertainment purposes of young children has shown a positive effect in the region of the child's brain that controls motor skills and is responsible for coordination with children exposed to bubbles at a young age showing measurably better motion skills that those who were not.
17th-century Flemish paintings show children blowing bubbles with clay pipes verifying soap bubbles being used as entertainment for at least 400 years. The London based firm of A. & F. Pears created a famous advertisement campaign for its soaps in 1886 using a painting by Millais of a child playing with bubbles. A Chicago company called Chemtoy began selling bubble solution in the 1940s, and they have been popular with children ever since. According to one industry estimate, retailers sell around 200 million bottles annually.
A bubble is made of transparent water enclosing transparent air. However the soap film is as thin as the visible light wavelength, resulting in interferences. This creates iridescence which, together with the bubble's spherical shape and fragility, contributes to its magical effect on children and adults alike. Each colour is the result of varying thicknesses of soap bubble film. Tom Noddy (who featured in the second episode of Marcus du Sautoy's The Code) gave the analogy of looking at a contour map of the bubbles' surface. However, it has become a challenge to produce artificially coloured bubbles.
Byron, Melody & Enoch Swetland invented a patented non-toxic bubble (Tekno Bubbles) that glow under UV lighting. These bubbles look like ordinary high quality "clear" bubbles under normal lighting, but glow when exposed to true UV light. The brighter the UV lighting, the brighter they glow. The family sold them world-wide, but has since sold their company.
Adding coloured dye to bubble mixtures fails to produce coloured bubbles, because the dye attaches to the water molecules as opposed to the surfactant. Therefore, a colourless bubble forms with the dye falling to a point at the base. Dye chemist Dr. Ram Sabnis has developed a lactone dye that sticks to the surfactants, enabling brightly coloured bubbles to be formed. Crystal violet lactone is an example. Another man named Tim Kehoe invented a coloured bubble which loses its colour when exposed to pressure or oxygen, which he is now marketing online as Zubbles, which are non-toxic and non-staining. In 2010, Japanese astronaut Naoko Yamazaki demonstrated that it is possible to create coloured bubbles in microgravity. The reason is that the water molecules are spread evenly around the bubble in the low-gravity environment.
If Soap bubbles blown into air that is below a temperature of −15 °C (5 °F) they will freeze when they touch a surface. The air inside will gradually diffuse out, causing the bubble to crumble under its own weight. At temperatures below about −25 °C (−13 °F), bubbles will freeze in the air and may shatter when hitting the ground. When a bubble is blown with warm air, the bubble will freeze to an almost perfect sphere at first, but when the warm air cools, and a reduction in volume occurs, there will be a partial collapse of the bubble. A bubble, created successfully at this low temperature, will always be rather small; it will freeze quickly and will shatter if increased further.
Soap bubble performances combine entertainment with artistic achievement. They require a high degree of skill. Some performers use common commercially available bubble liquids while others compose their own solutions. Some artists create giant bubbles or tubes, often enveloping objects or even humans. Others manage to create bubbles forming cubes, tetrahedra and other shapes and forms. Bubbles are sometimes handled with bare hands. To add to the visual experience, they are sometimes filled with smoke, vapour or helium and combined with laser lights or fire. Soap bubbles can be filled with a flammable gas such as natural gas and then ignited.
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