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Red, pure green and blue LEDs of the 5mm diffused type
|Invented||Oleg Losev (1927)|
James R. Biard (1961)
Nick Holonyak (1962)
|Pin configuration||anode and cathode|
Red, pure green and blue LEDs of the 5mm diffused type
|Invented||Oleg Losev (1927)|
James R. Biard (1961)
Nick Holonyak (1962)
|Pin configuration||anode and cathode|
A light-emitting diode (LED) is a semiconductor light source. LEDs are used as indicator lamps in many devices and are increasingly used for general lighting. Appearing as practical electronic components in 1962, early LEDs emitted low-intensity red light, but modern versions are available across the visible, ultraviolet, and infrared wavelengths, with very high brightness.
When a light-emitting diode is switched on, electrons are able to recombine with holes within the device, releasing energy in the form of photons. This effect is called electroluminescence, and the color of the light (corresponding to the energy of the photon) is determined by the energy band gap of the semiconductor. An LED is often small in area (less than 1 mm2), and integrated optical components may be used to shape its radiation pattern. LEDs have many advantages over incandescent light sources including lower energy consumption, longer lifetime, improved physical robustness, smaller size, and faster switching. However, LEDs powerful enough for room lighting are relatively expensive, and require more precise current and heat management than compact fluorescent lamp sources of comparable output.
Light-emitting diodes are used in applications as diverse as aviation lighting, automotive lighting, advertising, general lighting, and traffic signals. LEDs have allowed new text, video displays, and sensors to be developed, while their high switching rates are also useful in advanced communications technology. Infrared LEDs are also used in the remote control units of many commercial products including televisions, DVD players and other domestic appliances. LEDs are also used in seven-segment display.
Electroluminescence as a phenomenon was discovered in 1907 by the British experimenter H. J. Round of Marconi Labs, using a crystal of silicon carbide and a cat's-whisker detector. Russian Oleg Losev reported creation of the first LED in 1927. His research was distributed in Russian, German and British scientific journals, but no practical use was made of the discovery for several decades. Rubin Braunstein of the Radio Corporation of America reported on infrared emission from gallium arsenide (GaAs) and other semiconductor alloys in 1955. Braunstein observed infrared emission generated by simple diode structures using gallium antimonide (GaSb), GaAs, indium phosphide (InP), and silicon-germanium (SiGe) alloys at room temperature and at 77 Kelvin.
In 1961 American experimenters James R. Biard and Gary Pittman, working at Texas Instrument, found that GaAs emitted infrared radiation when electric current was applied. The two were able to establish the priority of their work based on engineering notebooks, and received the first US patent for the LED (although the light emitted was infrared).
The first practical visible-spectrum (red) LED was developed in 1962 by Nick Holonyak, Jr., while working at General Electric Company. Holonyak first reported this breakthrough in the journal Applied Physics Letters on the December 1, 1962. Holonyak is seen as the "father of the light-emitting diode". M. George Craford, a former graduate student of Holonyak, invented the first yellow LED and improved the brightness of red and red-orange LEDs by a factor of ten in 1972. In 1976, T. P. Pearsall created the first high-brightness, high-efficiency LEDs for optical fiber telecommunications by inventing new semiconductor materials specifically adapted to optical fiber transmission wavelengths.
The first commercial LEDs were commonly used as replacements for incandescent and neon indicator lamps, and in seven-segment displays, first in expensive equipment such as laboratory and electronics test equipment, then later in such appliances as TVs, radios, telephones, calculators, and even watches (see list of signal uses). Until 1968, visible and infrared LEDs were extremely costly, in the order of US$200 per unit, and so had little practical use. The Monsanto Company was the first organization to mass-produce visible LEDs, using gallium arsenide phosphide (GaAsP) in 1968 to produce red LEDs suitable for indicators. Hewlett Packard (HP) introduced LEDs in 1968, initially using GaAsP supplied by Monsanto. These red LEDs were bright enough only for use as indicators, as the light output was not enough to illuminate an area. Readouts in calculators were so small that plastic lenses were built over each digit to make them legible. Later, other colors became widely available and appeared in appliances and equipment. In the 1970s commercially successful LED devices at less than five cents each were produced by Fairchild Optoelectronics. These devices employed compound semiconductor chips fabricated with the planar process invented by Dr. Jean Hoerni at Fairchild Semiconductor. The combination of planar processing for chip fabrication and innovative packaging methods enabled the team at Fairchild led by optoelectronics pioneer Thomas Brandt to achieve the needed cost reductions. These methods continue to be used by LED producers.
As LED materials technology grew more advanced, light output rose, while maintaining efficiency and reliability at acceptable levels. The invention and development of the high-power white-light LED led to use for illumination, and is slowly replacing incandescent and fluorescent lighting (see list of illumination applications).
Most LEDs were made in the very common 5 mm T1¾ and 3 mm T1 packages, but with rising power output, it has grown increasingly necessary to shed excess heat to maintain reliability, so more complex packages have been adapted for efficient heat dissipation. Packages for state-of-the-art high-power LEDs bear little resemblance to early LEDs.
The first high-brightness blue LED was demonstrated by Shuji Nakamura of Nichia Corporation in 1994 and was based on InGaN. Its development built on critical developments in GaN nucleation on sapphire substrates and the demonstration of p-type doping of GaN, developed by Isamu Akasaki and H. Amano in Nagoya. In 1995, Alberto Barbieri at the Cardiff University Laboratory (GB) investigated the efficiency and reliability of high-brightness LEDs and demonstrated a "transparent contact" LED using indium tin oxide (ITO) on (AlGaInP/GaAs). The existence of blue LEDs and high-efficiency LEDs quickly led to the development of the first white LED, which employed a Y
12:Ce, or "YAG", phosphor coating to mix down-converted yellow light with blue to produce light that appears white. Nakamura was awarded the 2006 Millennium Technology Prize for his invention.
The development of LED technology has caused their efficiency and light output to rise exponentially, with a doubling occurring approximately every 36 months since the 1960s, in a way similar to Moore's law. This trend is generally attributed to the parallel development of other semiconductor technologies and advances in optics and material science, and has been called Haitz's law after Dr. Roland Haitz.
In 2001 and 2002, processes for growing gallium nitride (GaN) LEDs on silicon were successfully demonstrated. In January 2012, Osram demonstrated high-power InGaN LEDs grown on Silicon substrates commercially. It has been speculated that the use of six-inch silicon wafers instead of two-inch sapphire wafers and epitaxy manufacturing processes could reduce production costs by up to 90%.
The LED consists of a chip of semiconducting material doped with impurities to create a p-n junction. As in other diodes, current flows easily from the p-side, or anode, to the n-side, or cathode, but not in the reverse direction. Charge-carriers—electrons and holes—flow into the junction from electrodes with different voltages. When an electron meets a hole, it falls into a lower energy level and releases energy in the form of a photon.
The wavelength of the light emitted, and thus its color, depends on the band gap energy of the materials forming the p-n junction. In silicon or germanium diodes, the electrons and holes recombine by a non-radiative transition, which produces no optical emission, because these are indirect band gap materials. The materials used for the LED have a direct band gap with energies corresponding to near-infrared, visible, or near-ultraviolet light.
LED development began with infrared and red devices made with gallium arsenide. Advances in materials science have enabled making devices with ever-shorter wavelengths, emitting light in a variety of colors.
LEDs are usually built on an n-type substrate, with an electrode attached to the p-type layer deposited on its surface. P-type substrates, while less common, occur as well. Many commercial LEDs, especially GaN/InGaN, also use sapphire substrate.
Most materials used for LED production have very high refractive indices. This means that much light will be reflected back into the material at the material/air surface interface. Thus, light extraction in LEDs is an important aspect of LED production, subject to much research and development.
Bare uncoated semiconductors such as silicon exhibit a very high refractive index relative to open air, which prevents passage of photons at sharp angles relative to the air-contacting surface of the semiconductor. This property affects both the light-emission efficiency of LEDs as well as the light-absorption efficiency of photovoltaic cells. The refractive index of silicon is 3.96 (590 nm), while air is 1.0002926.
In general, a flat-surface uncoated LED semiconductor chip will emit light only perpendicular to the semiconductor's surface, and a few degrees to the side, in a cone shape referred to as the light cone, cone of light, or the escape cone. The maximum angle of incidence is referred to as the critical angle. When this angle is exceeded, photons no longer escape the semiconductor but are instead reflected internally inside the semiconductor crystal as if it were a mirror.
Internal reflections can escape through other crystalline faces, if the incidence angle is low enough and the crystal is sufficiently transparent to not re-absorb the photon emission. But for a simple square LED with 90-degree angled surfaces on all sides, the faces all act as equal angle mirrors. In this case most of the light can not escape and is lost as waste heat in the crystal.
A convoluted chip surface with angled facets similar to a jewel or fresnel lens can increase light output by allowing light to be emitted perpendicular to the chip surface while far to the sides of the photon emission point.
The ideal shape of a semiconductor with maximum light output would be a microsphere with the photon emission occurring at the exact center, with electrodes penetrating to the center to contact at the emission point. All light rays emanating from the center would be perpendicular to the entire surface of the sphere, resulting in no internal reflections. A hemispherical semiconductor would also work, with the flat back-surface serving as a mirror to back-scattered photons.
Many LED semiconductor chips are encapsulated or potted in clear or colored molded plastic shells. The plastic shell has three purposes:
The third feature helps to boost the light emission from the semiconductor by acting as a diffusing lens, allowing light to be emitted at a much higher angle of incidence from the light cone than the bare chip is able to emit alone.
Typical indicator LEDs are designed to operate with no more than 30–60 milliwatts (mW) of electrical power. Around 1999, Philips Lumileds introduced power LEDs capable of continuous use at one watt. These LEDs used much larger semiconductor die sizes to handle the large power inputs. Also, the semiconductor dies were mounted onto metal slugs to allow for heat removal from the LED die.
One of the key advantages of LED-based lighting sources is high luminous efficacy. White LEDs quickly matched and overtook the efficacy of standard incandescent lighting systems. In 2002, Lumileds made five-watt LEDs available with a luminous efficacy of 18–22 lumens per watt (lm/W). For comparison, a conventional incandescent light bulb of 60–100 watts emits around 15 lm/W, and standard fluorescent lights emit up to 100 lm/W. A recurring problem is that efficacy falls sharply with rising current. This effect is known as droop and effectively limits the light output of a given LED, raising heating more than light output for higher current.
|Color||Wavelength range (nm)||Typical efficacy (lm/W)||Typical efficiency (W/W)|
|Red||620 < λ < 645||72||0.39|
|Red-orange||610 < λ < 620||98||0.29|
|Green||520 < λ < 550||93||0.15|
|Cyan||490 < λ < 520||75||0.26|
|Blue||460 < λ < 490||37||0.35|
In September 2003, a new type of blue LED was demonstrated by the company Cree Inc. to provide 24 mW at 20 milliamperes (mA). This produced a commercially packaged white light giving 65 lm/W at 20 mA, becoming the brightest white LED commercially available at the time, and more than four times as efficient as standard incandescents. In 2006, they demonstrated a prototype with a record white LED luminous efficacy of 131 lm/W at 20 mA. Nichia Corporation has developed a white LED with luminous efficacy of 150 lm/W at a forward current of 20 mA. Cree's XLamp XM-L LEDs, commercially available in 2011, produce 100 lm/W at their full power of 10 W, and up to 160 lm/W at around 2 W input power. In 2012, Cree announced a white LED giving 254 lm/W.
Practical general lighting needs high-power LEDs, of one watt or more. Typical operating currents for such devices begin at 350 mA.
Note that these efficiencies are for the LED chip only, held at low temperature in a lab. Lighting works at higher temperature and with drive circuit losses, so efficiencies are much lower. United States Department of Energy (DOE) testing of commercial LED lamps designed to replace incandescent lamps or CFLs showed that average efficacy was still about 46 lm/W in 2009 (tested performance ranged from 17 lm/W to 79 lm/W).
Cree issued a press release on February 3, 2010 about a laboratory prototype LED achieving 208 lm/W at room temperature. The correlated color temperature was reported to be 4579 K. In December 2012 Cree issued another press release announcing commercial availability of 200 lm/W LED at room temperature.
Solid-state devices such as LEDs are subject to very limited wear and tear if operated at low currents and at low temperatures. Many of the LEDs made in the 1970s and 1980s are still in service in the early 21st century. Typical lifetimes quoted are 25,000 to 100,000 hours, but heat and current settings can extend or shorten this time significantly. 
The most common symptom of LED (and diode laser) failure is the gradual lowering of light output and loss of efficiency. Sudden failures, although rare, can occur as well. Early red LEDs were notable for their short service life. With the development of high-power LEDs the devices are subjected to higher junction temperatures and higher current densities than traditional devices. This causes stress on the material and may cause early light-output degradation. To quantitatively classify useful lifetime in a standardized manner it has been suggested to use the terms L70 and L50, which is the time it will take a given LED to reach 70% and 50% light output respectively.
LED performance is temperature dependent. Most manufacturers' published ratings of LEDs are for an operating temperature of 25 °C. LEDs used outdoors, such as traffic signals or in-pavement signal lights, and that are utilized in climates where the temperature within the light fixture gets very hot, could result in low signal intensities or even failure.
LED light output rises at lower temperatures, leveling off, depending on type, at around −30 °C. Thus, LED technology may be a good replacement in uses such as supermarket freezer lighting and will last longer than other technologies. Because LEDs emit less heat than incandescent bulbs, they are an energy-efficient technology for uses such as in freezers and refrigerators. However, because they emit little heat, ice and snow may build up on the LED light fixture in colder climates. Similarly, this lack of waste heat generation has been observed to sometimes cause significant problems with street traffic signals and airport runway lighting in snow-prone areas. In response to this problem, some LED lighting systems have been designed with an added heating circuit at the expense of reduced overall electrical efficiency of the system; additionally, research has been done to develop heat sink technologies that will transfer heat produced within the junction to appropriate areas of the light fixture.
Conventional LEDs are made from a variety of inorganic semiconductor materials. The following table shows the available colors with wavelength range, voltage drop and material:
|Color||Wavelength [nm]||Voltage drop [ΔV]||Semiconductor material|
|Infrared||λ > 760||ΔV < 1.63||Gallium arsenide (GaAs)|
Aluminium gallium arsenide (AlGaAs)
|Red||610 < λ < 760||1.63 < ΔV < 2.03||Aluminium gallium arsenide (AlGaAs)|
Gallium arsenide phosphide (GaAsP)
Aluminium gallium indium phosphide (AlGaInP)
Gallium(III) phosphide (GaP)
|Orange||590 < λ < 610||2.03 < ΔV < 2.10||Gallium arsenide phosphide (GaAsP)|
Aluminium gallium indium phosphide (AlGaInP)
Gallium(III) phosphide (GaP)
|Yellow||570 < λ < 590||2.10 < ΔV < 2.18||Gallium arsenide phosphide (GaAsP)|
Aluminium gallium indium phosphide (AlGaInP)
Gallium(III) phosphide (GaP)
|Green||500 < λ < 570||1.9 < ΔV < 4.0||Traditional green:|
Gallium(III) phosphide (GaP)
Aluminium gallium indium phosphide (AlGaInP)
Aluminium gallium phosphide (AlGaP)
Indium gallium nitride (InGaN) / Gallium(III) nitride (GaN)
|Blue||450 < λ < 500||2.48 < ΔV < 3.7||Zinc selenide (ZnSe)|
Indium gallium nitride (InGaN)
Silicon carbide (SiC) as substrate
Silicon (Si) as substrate—under development
|Violet||400 < λ < 450||2.76 < ΔV < 4.0||Indium gallium nitride (InGaN)|
|Purple||multiple types||2.48 < ΔV < 3.7||Dual blue/red LEDs,|
blue with red phosphor,
or white with purple plastic
|Ultraviolet||λ < 400||3.1 < ΔV < 4.4||Diamond (235 nm)|
Boron nitride (215 nm)
Aluminium nitride (AlN) (210 nm)
Aluminium gallium nitride (AlGaN)
Aluminium gallium indium nitride (AlGaInN)—down to 210 nm
|Pink||multiple types||ΔV ~ 3.3||Blue with one or two phosphor layers:|
yellow with red, orange or pink phosphor added afterwards,
or white phosphors with pink pigment or dye over top.
|White||Broad spectrum||ΔV = 3.5||Blue/UV diode with yellow phosphor|
Current bright blue LEDs are based on the wide band gap semiconductors GaN (gallium nitride) and InGaN (indium gallium nitride). They can be added to existing red and green LEDs to produce the impression of white light. Modules combining the three colors are used in big video screens and in adjustable-color fixtures.
The first blue LEDs using gallium nitride were made in 1971 by Jacques Pankove at RCA Laboratories. These devices had too little light output to be of practical use and research into gallium nitride devices slowed. In August 1989, Cree Inc. introduced the first commercially available blue LED based on the indirect bandgap semiconductor, silicon carbide. SiC LEDs had very low efficiency, no more than about 0.03%, but did emit in the blue portion of the visible light spectrum.
In the late 1980s, key breakthroughs in GaN epitaxial growth and p-type doping ushered in the modern era of GaN-based optoelectronic devices. Building upon this foundation, in 1993 high-brightness blue LEDs were demonstrated. High-brightness blue LEDs invented by Shuji Nakamura of Nichia Corporation using gallium nitride revolutionized LED lighting, making high-power light sources practical.
By the late 1990s, blue LEDs had become widely available. They have an active region consisting of one or more InGaN quantum wells sandwiched between thicker layers of GaN, called cladding layers. By varying the relative In/Ga fraction in the InGaN quantum wells, the light emission can in theory be varied from violet to amber. Aluminium gallium nitride (AlGaN) of varying Al/Ga fraction can be used to manufacture the cladding and quantum well layers for ultraviolet LEDs, but these devices have not yet reached the level of efficiency and technological maturity of InGaN/GaN blue/green devices. If un-alloyed GaN is used in this case to form the active quantum well layers, the device will emit near-ultraviolet light with a peak wavelength centred around 365 nm. Green LEDs manufactured from the InGaN/GaN system are far more efficient and brighter than green LEDs produced with non-nitride material systems, but practical devices still exhibit efficiency too low for high-brightness applications.
With nitrides containing aluminium, most often AlGaN and AlGaInN, even shorter wavelengths are achievable. Ultraviolet LEDs in a range of wavelengths are becoming available on the market. Near-UV emitters at wavelengths around 375–395 nm are already cheap and often encountered, for example, as black light lamp replacements for inspection of anti-counterfeiting UV watermarks in some documents and paper currencies. Shorter-wavelength diodes, while substantially more expensive, are commercially available for wavelengths down to 240 nm. As the photosensitivity of microorganisms approximately matches the absorption spectrum of DNA, with a peak at about 260 nm, UV LED emitting at 250–270 nm are to be expected in prospective disinfection and sterilization devices. Recent research has shown that commercially available UVA LEDs (365 nm) are already effective disinfection and sterilization devices.
There are two primary ways of producing white light-emitting diodes (WLEDs), LEDs that generate high-intensity white light. One is to use individual LEDs that emit three primary colors—red, green, and blue—and then mix all the colors to form white light. The other is to use a phosphor material to convert monochromatic light from a blue or UV LED to broad-spectrum white light, much in the same way a fluorescent light bulb works.
There are three main methods of mixing colors to produce white light from an LED:
Because of metamerism, it is possible to have quite different spectra that appear white. However, the appearance of objects illuminated by that light may vary as the spectrum varies.
White light can be formed by mixing differently colored lights; the most common method is to use red, green, and blue (RGB). Hence the method is called multi-color white LEDs (sometimes referred to as RGB LEDs). Because these need electronic circuits to control the blending and diffusion of different colors, and because the individual color LEDs typically have slightly different emission patterns (leading to variation of the color depending on direction) even if they are made as a single unit, these are seldom used to produce white lighting. Nevertheless, this method is particularly interesting in many uses because of the flexibility of mixing different colors, and, in principle, this mechanism also has higher quantum efficiency in producing white light.
There are several types of multi-color white LEDs: di-, tri-, and tetrachromatic white LEDs. Several key factors that play among these different methods, include color stability, color rendering capability, and luminous efficacy. Often, higher efficiency will mean lower color rendering, presenting a trade-off between the luminous efficiency and color rendering. For example, the dichromatic white LEDs have the best luminous efficacy (120 lm/W), but the lowest color rendering capability. However, although tetrachromatic white LEDs have excellent color rendering capability, they often have poor luminous efficiency. Trichromatic white LEDs are in between, having both good luminous efficacy (>70 lm/W) and fair color rendering capability.
One of the challenges is the development of more efficient green LEDs. The theoretical maximum for green LEDs is 683 lumens per watt but as of 2010 few green LEDs exceed even 100 lumens per watt. The blue and red LEDs get closer to their theoretical limits.
Multi-color LEDs offer not merely another means to form white light but a new means to form light of different colors. Most perceivable colors can be formed by mixing different amounts of three primary colors. This allows precise dynamic color control. As more effort is devoted to investigating this method, multi-color LEDs should have profound influence on the fundamental method that we use to produce and control light color. However, before this type of LED can play a role on the market, several technical problems must be solved. These include that this type of LED's emission power decays exponentially with rising temperature, resulting in a substantial change in color stability. Such problems inhibit and may preclude industrial use. Thus, many new package designs aimed at solving this problem have been proposed and their results are now being reproduced by researchers and scientists.
Correlated color temperature (CCT) dimming for LED technology is regarded as a difficult task, since binning, age and temperature drift effects of LEDs change the actual color value output. Feedback loop systems are used for example with color sensors, to actively monitor and control the color output of multiple color mixing LEDs.
This method involves coating LEDs of one color (mostly blue LEDs made of InGaN) with phosphors of different colors to form white light; the resultant LEDs are called phosphor-based or phosphor-converted white LEDs (pcLEDs). A fraction of the blue light undergoes the Stokes shift being transformed from shorter wavelengths to longer. Depending on the color of the original LED, phosphors of different colors can be employed. If several phosphor layers of distinct colors are applied, the emitted spectrum is broadened, effectively raising the color rendering index (CRI) value of a given LED.
Phosphor-based LED efficiency losses are due to the heat loss from the Stokes shift and also other phosphor-related degradation issues. Their luminous efficacies compared to normal LEDs depend on the spectral distribution of the resultant light output and the original wavelength of the LED itself. For example, the luminous efficacy of a typical YAG yellow phosphor based white LED ranges from 3 to 5 times the luminous efficacy of the original blue LED because of the human eye's greater sensitivity to yellow than to blue (as modeled in the luminosity function). Due to the simplicity of manufacturing the phosphor method is still the most popular method for making high-intensity white LEDs. The design and production of a light source or light fixture using a monochrome emitter with phosphor conversion is simpler and cheaper than a complex RGB system, and the majority of high-intensity white LEDs presently on the market are manufactured using phosphor light conversion.
Among the challenges being faced to improve the efficiency of LED-based white light sources is the development of more efficient phosphors. As of 2010, the most efficient yellow phosphor is still the YAG phosphor, with less than 10% Stoke shift loss. Losses attributable to internal optical losses due to re-absorption in the LED chip and in the LED packaging itself account typically for another 10% to 30% of efficiency loss. Currently, in the area of phosphor LED development, much effort is being spent on optimizing these devices to higher light output and higher operation temperatures. For instance, the efficiency can be raised by adapting better package design or by using a more suitable type of phosphor. Conformal coating process is frequently used to address the issue of varying phosphor thickness.
Some phosphor-based white LEDs encapsulate InGaN blue LEDs inside phosphor-coated epoxy. Alternatively, the LED might be paired with a remote phosphor, a preformed polycarbonate piece coated with the phosphor material. Remote phosphors provide more diffuse light, which is desirable for many applications. Remote phosphor designs are also more tolerant of variations in the LED emissions spectrum. A common yellow phosphor material is cerium-doped yttrium aluminium garnet (Ce3+:YAG).
White LEDs can also be made by coating near-ultraviolet (NUV) LEDs with a mixture of high-efficiency europium-based phosphors that emit red and blue, plus copper and aluminium-doped zinc sulfide (ZnS:Cu, Al) that emits green. This is a method analogous to the way fluorescent lamps work. This method is less efficient than blue LEDs with YAG:Ce phosphor, as the Stokes shift is larger, so more energy is converted to heat, but yields light with better spectral characteristics, which render color better. Due to the higher radiative output of the ultraviolet LEDs than of the blue ones, both methods offer comparable brightness. A concern is that UV light may leak from a malfunctioning light source and cause harm to human eyes or skin.
Another method used to produce experimental white light LEDs used no phosphors at all and was based on homoepitaxially grown zinc selenide (ZnSe) on a ZnSe substrate that simultaneously emitted blue light from its active region and yellow light from the substrate.
In an organic light-emitting diode (OLED), the electroluminescent material comprising the emissive layer of the diode is an organic compound. The organic material is electrically conductive due to the delocalization of pi electrons caused by conjugation over all or part of the molecule, and the material therefore functions as an organic semiconductor. The organic materials can be small organic molecules in a crystalline phase, or polymers.
The potential advantages of OLEDs include thin, low-cost displays with a low driving voltage, wide viewing angle, and high contrast and color gamut. Polymer LEDs have the added benefit of printable and flexible displays. OLEDs have been used to make visual displays for portable electronic devices such as cellphones, digital cameras, and MP3 players while possible future uses include lighting and televisions.
Quantum dots (QD) are semiconductor nanocrystals that possess unique optical properties. Their emission color can be tuned from the visible throughout the infrared spectrum. This allows quantum dot LEDs to create almost any color on the CIE diagram. This provides more color options and better color rendering than white LEDs. Quantum-dot LEDs are available in the same package types as traditional phosphor-based LEDs.There are two types of schemes for QD excitation. One uses photo excitation with a primary light source LED (typically blue or UV LEDs are used). The other is direct electrical excitation first demonstrated by Alivisatos et al.
One example of the photo-excitation scheme is a method developed by Michael Bowers, at Vanderbilt University in Nashville, involving coating a blue LED with quantum dots that glow white in response to the blue light from the LED. This method emits a warm, yellowish-white light similar to that made by incandescent bulbs. Quantum dots are also being considered for use in white light-emitting diodes in liquid crystal display (LCD) televisions.
The major difficulty in using quantum dots-based LEDs is the insufficient stability of QDs under prolonged irradiation. In February 2011 scientists at PlasmaChem GmbH could synthesize quantum dots for LED applications and build a light converter on their basis, which could efficiently convert light from blue to any other color for many hundred hours. Such QDs can be used to emit visible or near infrared light of any wavelength being excited by light with a shorter wavelength.
The structure of QD-LEDs used for the electrical-excitation scheme is similar to basic design of OLED. A layer of quantum dots is sandwiched between layers of electron-transporting and hole-transporting materials. An applied electric field causes electrons and holes to move into the quantum dot layer and recombine forming an exciton that excites a QD. This scheme is commonly studied for quantum dot display. The tunability of emission wavelengths and narrow bandwidth is also beneficial as excitation sources for fluorescence imaging. Fluorescence near-field scanning optical microscopy (NSOM) utilizing an integrated QD-LED has been demonstrated.
The main types of LEDs are miniature, high power devices and custom designs such as alphanumeric or multi-color.
These are mostly single-die LEDs used as indicators, and they come in various sizes from 2 mm to 8 mm, through-hole and surface mount packages. They usually do not use a separate heat sink. Typical current ratings ranges from around 1 mA to above 20 mA. The small size sets a natural upper boundary on power consumption due to heat caused by the high current density and need for a heat sink.
Common package shapes include round, with a domed or flat top, rectangular with a flat top (as used in bar-graph displays), and triangular or square with a flat top. The encapsulation may also be clear or tinted to improve contrast and viewing angle.
There are three main categories of miniature single die LEDs:
|This section contains a gallery of images.|
Medium-power LEDs are often through-hole-mounted and mostly utilized when an output of just a few lumen is needed. They sometimes have the diode mounted to four leads (two cathode leads, two anode leads) for better heat conduction and carry an integrated lens. An example of this is the Superflux package, from Philips Lumileds. These LEDs are most commonly used in light panels, emergency lighting, and automotive tail-lights. Due to the larger amount of metal in the LED, they are able to handle higher currents (around 100 mA). The higher current allows for the higher light output required for tail-lights and emergency lighting.
High-power LEDs (HPLEDs) or high-output LEDs (HO-LEDs) can be driven at currents from hundreds of mA to more than an ampere, compared with the tens of mA for other LEDs. Some can emit over a thousand lumens. LED power densities up to 300 W/cm2 have been achieved. Since overheating is destructive, the HPLEDs must be mounted on a heat sink to allow for heat dissipation. If the heat from a HPLED is not removed, the device will fail in seconds. One HPLED can often replace an incandescent bulb in a flashlight, or be set in an array to form a powerful LED lamp.
Some well-known HPLEDs in this category are the Nichia 19 series, Lumileds Rebel Led, Osram Opto Semiconductors Golden Dragon, and Cree X-lamp. As of September 2009, some HPLEDs manufactured by Cree Inc. now exceed 105 lm/W  (e.g. the XLamp XP-G LED chip emitting Cool White light) and are being sold in lamps intended to replace incandescent, halogen, and even fluorescent lights, as LEDs grow more cost competitive.
The impact of Haitz's law which describes the exponential rise in light output of LEDs over time can be readily seen in year over year increases in lumen output and efficiency. For example, the CREE XP-G series LED achieved 105 lm/W in 2009, while Nichia released the 19 series with a typical efficacy of 140 lm/W in 2010.
LEDs have been developed by Seoul Semiconductor that can operate on AC power without the need for a DC converter. For each half-cycle, part of the LED emits light and part is dark, and this is reversed during the next half-cycle. The efficacy of this type of HPLED is typically 40 lm/W. A large number of LED elements in series may be able to operate directly from line voltage. In 2009, Seoul Semiconductor released a high DC voltage LED capable of being driven from AC power with a simple controlling circuit. The low-power dissipation of these LEDs affords them more flexibility than the original AC LED design.
The current–voltage characteristic of an LED is similar to other diodes, in that the current is dependent exponentially on the voltage (see Shockley diode equation). This means that a small change in voltage can cause a large change in current. If the maximum voltage rating is exceeded by a small amount, the current rating may be exceeded by a large amount, potentially damaging or destroying the LED. The typical solution is to use constant-current power supplies, or driving the LED at a voltage much below the maximum rating. Since most common power sources (batteries, mains) are constant-voltage sources, most LED fixtures must include a power converter, at least a current-limiting resistor. However, the high resistance of 3 V coin cells combined with the high differential resistance of nitride-based LEDs makes it possible to power such an LED from such a coin cell without an external resistor.
As with all diodes, current flows easily from p-type to n-type material. However, no current flows and no light is emitted if a small voltage is applied in the reverse direction. If the reverse voltage grows large enough to exceed the breakdown voltage, a large current flows and the LED may be damaged. If the reverse current is sufficiently limited to avoid damage, the reverse-conducting LED is a useful noise diode.
The vast majority of devices containing LEDs are "safe under all conditions of normal use", and so are classified as "Class 1 LED product"/"LED Klasse 1". At present, only a few LEDs—extremely bright LEDs that also have a tightly focused viewing angle of 8° or less—could, in theory, cause temporary blindness, and so are classified as "Class 2". The Opinion of the French Agency for Food, Environmental and Occupational Health & Safety (ANSES) of 2010, on the health issues concerning LEDs, suggested banning public use of lamps which were in the moderate Risk Group 2, especially those with a high blue component in places frequented by children. In general, laser safety regulations—and the "Class 1", "Class 2", etc. system—also apply to LEDs.
While LEDs have the advantage over fluorescent lamps that they do not contain mercury, they may contain other hazardous metals such as lead and arsenic. A study published in 2011 states: "According to federal standards, LEDs are not hazardous except for low-intensity red LEDs, which leached Pb [lead] at levels exceeding regulatory limits (186 mg/L; regulatory limit: 5). However, according to California regulations, excessive levels of copper (up to 3892 mg/kg; limit: 2500), lead (up to 8103 mg/kg; limit: 1000), nickel (up to 4797 mg/kg; limit: 2000), or silver (up to 721 mg/kg; limit: 500) render all except low-intensity yellow LEDs hazardous."
LED uses fall into four major categories:
The low energy consumption, low maintenance and small size of LEDs has led to uses as status indicators and displays on a variety of equipment and installations. Large-area LED displays are used as stadium displays and as dynamic decorative displays. Thin, lightweight message displays are used at airports and railway stations, and as destination displays for trains, buses, trams, and ferries.
One-color light is well suited for traffic lights and signals, exit signs, emergency vehicle lighting, ships' navigation lights or lanterns (chromacity and luminance standards being set under the Convention on the International Regulations for Preventing Collisions at Sea 1972, Annex I and the CIE) and LED-based Christmas lights. In cold climates, LED traffic lights may remain snow covered. Red or yellow LEDs are used in indicator and alphanumeric displays in environments where night vision must be retained: aircraft cockpits, submarine and ship bridges, astronomy observatories, and in the field, e.g. night time animal watching and military field use.
Because of their long life, fast switching times, and their ability to be seen in broad daylight due to their high output and focus, LEDs have been used in brake lights for cars' high-mounted brake lights, trucks, and buses, and in turn signals for some time, but many vehicles now use LEDs for their rear light clusters. The use in brakes improves safety, due to a great reduction in the time needed to light fully, or faster rise time, up to 0.5 second faster than an incandescent bulb. This gives drivers behind more time to react. It is reported that at normal highway speeds, this equals one car length equivalent in increased time to react. In a dual intensity circuit (rear markers and brakes) if the LEDs are not pulsed at a fast enough frequency, they can create a phantom array, where ghost images of the LED will appear if the eyes quickly scan across the array. White LED headlamps are starting to be used. Using LEDs has styling advantages because LEDs can form much thinner lights than incandescent lamps with parabolic reflectors.
With the development of high-efficiency and high-power LEDs, it has become possible to use LEDs in lighting and illumination. Replacement light bulbs have been made, as well as dedicated fixtures and LED lamps. To encourage the shift to very high efficiency lighting, the US Department of Energy has created the L Prize competition. The Philips Lighting North America LED bulb won the first competition on August 3, 2011 after successfully completing 18 months of intensive field, lab, and product testing.
LEDs are used as street lights and in other architectural lighting where color changing is used. The mechanical robustness and long lifetime is used in automotive lighting on cars, motorcycles, and bicycle lights.
LEDs are used in aviation lighting. Airbus has used LED lighting in their Airbus A320 Enhanced since 2007, and Boeing plans its use in the 787. LEDs are also being used now in airport and heliport lighting. LED airport fixtures currently include medium-intensity runway lights, runway centerline lights, taxiway centerline and edge lights, guidance signs, and obstruction lighting.
LEDs are also suitable for backlighting for LCD televisions and lightweight laptop displays and light source for DLP projectors (See LED TV). RGB LEDs raise the color gamut by as much as 45%. Screens for TV and computer displays can be made thinner using LEDs for backlighting.
LEDs are used increasingly in aquarium lights. In particular for reef aquariums, LED lights provide an efficient light source with less heat output to help maintain optimal aquarium temperatures. LED-based aquarium fixtures also have the advantage of being manually adjustable to emit a specific color-spectrum for ideal coloration of corals, fish, and invertebrates while optimizing photosynthetically active radiation (PAR), which raises growth and sustainability of photosynthetic life such as corals, anemones, clams, and macroalgae. These fixtures can be electronically programmed to simulate various lighting conditions throughout the day, reflecting phases of the sun and moon for a dynamic reef experience. LED fixtures typically cost up to five times as much as similarly rated fluorescent or high-intensity discharge lighting designed for reef aquariums and are not as high output to date.[dated info]
The lack of IR or heat radiation makes LEDs ideal for stage lights using banks of RGB LEDs that can easily change color and decrease heating from traditional stage lighting, as well as medical lighting where IR-radiation can be harmful. In energy conservation, the lower heat output of LEDs also means air conditioning (cooling) systems have less heat to dispose of, reducing carbon dioxide emissions.
LEDs are small, durable and need little power, so they are used in hand held devices such as flashlights. LED strobe lights or camera flashes operate at a safe, low voltage, instead of the 250+ volts commonly found in xenon flashlamp-based lighting. This is especially useful in cameras on mobile phones, where space is at a premium and bulky voltage-raising circuitry is undesirable.
LEDs are used for infrared illumination in night vision uses including security cameras. A ring of LEDs around a video camera, aimed forward into a retroreflective background, allows chroma keying in video productions.
LEDs are used in mining operations, as cap lamps to provide light for miners. Research has been done to improve LEDs for mining, to reduce glare and to increase illumination, reducing risk of injury for the miners.
LEDs are now used commonly in all market areas from commercial to home use: standard lighting, AV, stage, theatrical, architectural, and public installations, and wherever artificial light is used.
LEDs are increasingly finding uses in medical and educational applications, for example as mood enhancement, and new technologies such as AmBX, exploiting LED versatility. NASA has even sponsored research for the use of LEDs to promote health for astronauts.
Light can be used to transmit broadband data, which is already implemented in IrDA standards using infrared LEDs. Because LEDs can cycle on and off millions of times per second, they can be wireless transmitters and access points for data transport. Lasers can also be modulated in this manner.
Efficient lighting is needed for sustainable architecture. In 2009, a typical 13-watt LED lamp emitted 450 to 650 lumens, which is equivalent to a standard 40-watt incandescent bulb. In 2011, LEDs have become more efficient, so that a 6-watt LED can easily achieve the same results. A standard 40-watt incandescent bulb has an expected lifespan of 1,000 hours, whereas an LED can continue to operate with reduced efficiency for more than 50,000 hours, 50 times longer than the incandescent bulb.
In the US, one kilowatt-hour of electricity will cause 1.34 pounds (610 g) of CO
2 emission. Assuming the average light bulb is on for 10 hours a day, one 40-watt incandescent bulb will cause 196 pounds (89 kg) of CO
2 emission per year. The 6-watt LED equivalent will only cause 30 pounds (14 kg) of CO
2 over the same time span. A building’s carbon footprint from lighting can be reduced by 85% by exchanging all incandescent bulbs for new LEDs.
LED light bulbs could be a cost-effective option for lighting a home or office space because of their very long lifetimes. Consumer use of LEDs as a replacement for conventional lighting system is currently hampered by the high cost and low efficiency of available products. 2009 DOE testing results showed an average efficacy of 35 lm/W, below that of typical CFLs, and as low as 9 lm/W, worse than standard incandescents. However, as of 2011, there are LED bulbs available as efficient as 150 lm/W and even inexpensive low-end models typically exceed 50 lm/W. The high initial cost of commercial LED bulbs is due to the expensive sapphire substrate, which is key to the production process. The sapphire apparatus must be coupled with a mirror-like collector to reflect light that would otherwise be wasted.
The light from LEDs can be modulated very quickly so they are used extensively in optical fiber and free space optics communications. This includes remote controls, such as for TVs, VCRs, and LED Computers, where infrared LEDs are often used. Opto-isolators use an LED combined with a photodiode or phototransistor to provide a signal path with electrical isolation between two circuits. This is especially useful in medical equipment where the signals from a low-voltage sensor circuit (usually battery-powered) in contact with a living organism must be electrically isolated from any possible electrical failure in a recording or monitoring device operating at potentially dangerous voltages. An optoisolator also allows information to be transferred between circuits not sharing a common ground potential.
Many sensor systems rely on light as the signal source. LEDs are often ideal as a light source due to the requirements of the sensors. LEDs are used as movement sensors, for example in optical computer mice. The Nintendo Wii's sensor bar uses infrared LEDs. Pulse oximeters use them for measuring oxygen saturation. Some flatbed scanners use arrays of RGB LEDs rather than the typical cold-cathode fluorescent lamp as the light source. Having independent control of three illuminated colors allows the scanner to calibrate itself for more accurate color balance, and there is no need for warm-up. Further, its sensors only need be monochromatic, since at any one time the page being scanned is only lit by one color of light. Touch sensing: Since LEDs can also be used as photodiodes, they can be used for both photo emission and detection. This could be used, for example, in a touch-sensing screen that registers reflected light from a finger or stylus.
Many materials and biological systems are sensitive to or dependent on light. Grow lights use LEDs to increase photosynthesis in plants and bacteria and viruses can be removed from water and other substances using UV LEDs for sterilization. Other uses are as UV curing devices for some ink and coating methods, and in LED printers.
Plant growers are interested in LEDs because they are more energy-efficient, emit less heat (can damage plants close to hot lamps), and can provide the optimum light frequency for plant growth and bloom periods compared to currently used grow lights: HPS (high-pressure sodium), metal-halide (MH) or CFL/low-energy. However, LEDs have not replaced these grow lights due to higher price. As mass production and LED kits develop, the LED products will become cheaper.
LEDs have also been used as a medium-quality voltage reference in electronic circuits. The forward voltage drop (e.g., about 1.7 V for a normal red LED) can be used instead of a Zener diode in low-voltage regulators. Red LEDs have the flattest I/V curve above the knee. Nitride-based LEDs have a fairly steep I/V curve and are useless for this purpose. Although LED forward voltage is far more current-dependent than a good Zener, Zener diodes are not widely available below voltages of about 3 V.
LEDs are an essential part of the illumination system in digital microscopes, such as those which can be directly attached to the USB port of a computer. Such USB microscopes and endoscopes enable images to be recorded and stored directly on the computer without use of a separate camera.
Machine vision systems often require bright and homogeneous illumination, so features of interest are easier to process. LEDs are often used for this purpose, and this is likely to remain one of their major uses until price drops low enough to make signaling and illumination uses more widespread. Barcode scanners are the most common example of machine vision, and many low cost ones use red LEDs instead of lasers. Optical computer mice are also another example of LEDs in machine vision, as it is used to provide an even light source on the surface for the miniature camera within the mouse. LEDs constitute a nearly ideal light source for machine vision systems for several reasons:
The size of the illuminated field is usually comparatively small and machine vision systems are often quite expensive, so the cost of the light source is usually a minor concern. However, it might not be easy to replace a broken light source placed within complex machinery, and here the long service life of LEDs is a benefit.
LED elements tend to be small and can be placed with high density over flat or even-shaped substrates (PCBs etc.) so that bright and homogeneous sources that direct light from tightly controlled directions on inspected parts can be designed. This can often be obtained with small, low-cost lenses and diffusers, helping to achieve high light densities with control over lighting levels and homogeneity. LED sources can be shaped in several configurations (spot lights for reflective illumination; ring lights for coaxial illumination; back lights for contour illumination; linear assemblies; flat, large format panels; dome sources for diffused, omnidirectional illumination).
LEDs can be easily strobed (in the microsecond range and below) and synchronized with imaging. High-power LEDs are available allowing well-lit images even with very short light pulses. This is often used to obtain crisp and sharp “still” images of quickly moving parts.
LEDs come in several different colors and wavelengths, allowing easy use of the best color for each need, where different color may provide better visibility of features of interest. Having a precisely known spectrum allows tightly matched filters to be used to separate informative bandwidth or to reduce disturbing effects of ambient light. LEDs usually operate at comparatively low working temperatures, simplifying heat management and dissipation. This allows using plastic lenses, filters, and diffusers. Waterproof units can also easily be designed, allowing use in harsh or wet environments (food, beverage, oil industries).
|This section contains a gallery of images.|
A large LED display behind a disc jockey
LED destination signs on buses, one with a colored route number
Traffic light using LED
LED panel light source used in an experiment on plant growth. The findings of such experiments may be used to grow food in space on long duration missions.
LED lights reacting dynamically to video feed via AmBX
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