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Flint is a hard, sedimentary cryptocrystalline form of the mineral quartz, categorized as a variety of chert. It occurs chiefly as nodules and masses in sedimentary rocks, such as chalks and limestones. Inside the nodule, flint is usually dark grey, black, green, white, or brown in colour, and often has a glassy or waxy appearance. A thin layer on the outside of the nodules is usually different in colour, typically white and rough in texture. From a petrological point of view, "flint" refers specifically to the form of chert which occurs in chalk or marly limestone. Similarly, "common chert" (sometimes referred to simply as "chert") occurs in limestone.
The exact mode of formation of flint is not yet clear but it is thought that it occurs as a result of chemical changes in compressed sedimentary rock formations, during the process of diagenesis. One hypothesis is that a gelatinous material fills cavities in the sediment, such as holes bored by crustaceans or molluscs and that this becomes silicified. This hypothesis certainly explains the complex shapes of flint nodules that are found. The source of dissolved silica in the porous media could be the spicules of silicious sponges. Certain types of flint, such as that from the south coast of England, contain trapped fossilised marine flora. Pieces of coral and vegetation have been found preserved like amber inside the flint. Thin slices of the stone often reveal this effect.
Flint was used in the manufacture of tools during the Stone Age as it splits into thin, sharp splinters called flakes or blades (depending on the shape) when struck by another hard object (such as a hammerstone made of another material). This process is referred to as knapping.
In Europe, some of the best toolmaking flint has come from Belgium (Obourg, flint mines of Spiennes), the coastal chalks of the English Channel, the Paris Basin, Thy in Jutland (flint mine at Hov), the Sennonian deposits of Rügen, Grimes Graves in England, the Upper Cretaceous chalk formation of Dobruja and the lower Danube (Balkan flint), the Cenomanian chalky marl formation of the Moldavian Plateau (Miorcani flint) and the Jurassic deposits of the Kraków area and Krzemionki in Poland. Flint mining is attested since the Palaeolithic, but became more common since the Neolithic (Michelsberg culture, Funnelbeaker culture).
When struck against steel, a flint edge will produce sparks. The hard flint edge shaves off a particle of the steel that exposes iron which reacts with oxygen from the atmosphere and can ignite the proper tinder. Prior to the wide availability of steel, rocks of iron pyrite would be used along with the flint, in a similar (but more time-consuming) way. These methods are popular in woodcraft, bushcraft, and among those who wish to use traditional skills.
While flints may be used in fire-lighting they should not be exposed to heating by fire. Stone fracturing can result from uneven molecule expansion, causing fragmentation when cohesion is exceeded.
To combat fragmentation, flint/chert may be heat-treated, being slowly brought up to a temperature of 150 to 260 °C (300 to 500 °F) for 24 hours, then slowly cooled to room temperature. This makes the material more homogenous and thus more "knappable" and produces tools with a cleaner, sharper cutting edge.
A later, major use of flint and steel was in the flintlock mechanism, used primarily in flintlock firearms, but also used on dedicated fire-starting tools. A piece of flint held in the jaws of a spring-loaded hammer, when released by a trigger, strikes a hinged piece of steel ("frizzen") at an angle, creating a shower of sparks and exposing a charge of priming powder. The sparks ignite the priming powder and that flame, in turn, ignites the main charge, propelling the ball, bullet, or shot through the barrel. While the military use of the flintlock declined after the adoption of the percussion cap from the 1840s onward, flintlock rifles and shotguns remain in use amongst recreational shooters.
Flint and steel used to strike sparks were superseded by ferrocerium (sometimes referred to as "flint", although not true flint, "mischmetal", "hot spark", "metal match", or "fire steel"). This man-made material, when scraped with any hard, sharp edge, produces sparks that are much hotter than obtained with natural flint and steel, allowing use of a wider range of tinders. Because it can produce sparks when wet and can start hundreds or thousands of fires when used correctly, ferrocerium is commonly included in survival kits. Ferrocerium is used in many cigarette lighters, where it is referred to as "flint".
Flint, knapped or unknapped, has been used since antiquity (for example at the Late Roman fort of Burgh Castle in Norfolk) up to the present day as a material for building stone walls, using lime mortar, and often combined with other available stone or brick rubble. It was most common in parts of southern England, where no good building stone was available locally, and brick-making not widespread until the later Middle Ages. It is especially associated with East Anglia, but also used in chalky areas stretching through Hampshire, Sussex, Surrey and Kent to Somerset. Flint was used in the construction of many churches, houses, and other buildings, for example the large stronghold of Framlingham Castle. Many different decorative effects have been achieved by using different types of knapping or arrangement and combinations with stone (flushwork), especially in the 15th and early 16th centuries.
A typical medieval wall (with modern memorial) at Canterbury Cathedral - knapped and unknapped ("cobble") flints are mixed with pieces of brick and other stones
Ruins of Thetford Priory show flints and mortar through the whole depth of the wall
Elaborate patterned flushwork at top (restored in 19th century) and flint and limestone chequers below. Norwich Cathedral
Flint pebbles are used as the media in ball mills to grind glazes and other raw materials for the ceramics industry. The pebbles are hand-selected based on colour; those having a tint of red, indicating high iron content, are discarded. The remaining blue-grey stones have a low content of chromophoric oxides and so are less deleterious to the colour of the ceramic composition after firing.
Until recently flint was also an important raw material in clay-based ceramic bodies produced in the UK. In preparation for use flint pebbles, frequently sourced from the coasts of South-East England or Western France, were calcined to around 1,000°C. This heat process both removed organic impurities and induced certain physical reactions, including converting some of the silica to cristobalite. After calcination the flint pebbles were milled to a fine particle size. However, the use flint has now been superseded by quartz. Because of the historical use of flint, the word "flint" is used by some potters, especially in the US, to refer to siliceous materials that are not flint.
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