# Exothermic reaction

An exothermic thermite reaction using iron(III) oxide. The sparks flying outwards are globules of molten iron trailing smoke in their wake.

An exothermic reaction is a chemical reaction that releases energy in the form of light or heat. It is the opposite of an endothermic reaction.[1]

Expressed in a chemical equation: reactants → products + energy

## Overview

An exothermic reaction is a chemical or physical reaction that releases heat. It gives out energy to its surroundings. The energy needed for the reaction to occur is less than the total energy released.[2]

When using a calorimeter, the change in heat of the calorimeter is equal to the opposite of the change in heat of the system. This means that when the medium in which the reaction is taking place gains heat, the reaction is exothermic.

The absolute amount of energy in a chemical system is extremely difficult to measure or calculate. The enthalpy change, ΔH, of a chemical reaction is much easier to measure and calculate. A bomb calorimeter is very suitable for measuring the energy change, ΔH, of a combustion reaction. Measured and calculated ΔH values are related to bond energies by:

ΔH = energy used in bond breaking reactions − energy released in bond making products
An energy profile of an exothermic reaction

by definition the enthalpy change has a negative value:

ΔH < 0

in an exothermic reaction, gives a negative value for ΔH, since a larger value (the energy released in the reaction) is subtracted from a smaller value (the energy used for the reaction). For example, when hydrogen burns:

2H2 (g) + O2 (g) → 2H2O (g)
ΔH = −483.6 kJ/mol of O2 [3]

The most commonly available hand warmers make use of the oxidation of iron to achieve an exothermic reaction:

4Fe(s) + 3O2(g) → 2Fe2O3(s)

## Key points

• The concept and its opposite number endothermic relate to the enthalpy change in any process, not just chemical reactions.
• In endergonic reactions and exergonic reactions it is the sign of the Gibbs free energy that determines the equilibrium point, and not enthalpy. The related concepts endergonic and exergonic apply to all physical processes.
• The conceptually related endotherm and exotherm are concepts in animal physiology.
• In quantum numbers, when any excited energy level goes down to its original level for example: when n=4 fall to n=2, energy is released so, it is exothermic.
• Where an exothermic reaction causes heating of the reaction vessel which is not controlled, the rate of reaction can increase, in turn causing heat to be evolved even more quickly . This positive feedback situation is known as thermal runaway. An explosion can also result from the problem.

## Measurement

Heat production or absorption in either a physical process or chemical reaction is measured using calorimetry. One common laboratory instrument is the reaction calorimeter, where the heat flow into or from the reaction vessel is monitored. The technique can be used to follow chemical reactions as well as physical processes such as crystallisation and dissolution.

Energy released is measured in Joule per mole. The reaction has a negative ΔH(heat change) value due to heat loss. e.g.: -123 J/mol